Title of article
New efficient ruthenium catalysts for racemization of alcohols at room temperature
Author/Authors
Csjernyik، نويسنده , , Gلbor and Bogلr، نويسنده , , Krisztiلn and Bنckvall، نويسنده , , Jan-E.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
4
From page
6799
To page
6802
Abstract
(η5-Pentaphenylcyclopentadienyl)RuCl(CO)2 was found to catalyze efficiently the racemization of chiral alcohols such as (S)-1-phenylethanol, (S)-1-phenylpropan-2-ol, (S)-4-phenylbutan-2-ol and (S)-4-methoxy-1-phenylethanol at room temperature in the presence of a base. The catalytic activity of three other Ru(II) complexes was also investigated. The effects of halide and solvent were studied as well.
Journal title
Tetrahedron Letters
Serial Year
2004
Journal title
Tetrahedron Letters
Record number
1843164
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