Title of article
Reactivity of a kinetically stabilized 1,3,6-triphosphafulvene toward some nucleophiles
Author/Authors
Ito، نويسنده , , Shigekazu and Miyake، نويسنده , , Hideaki and Sugiyama، نويسنده , , Hiroki and Yoshifuji، نويسنده , , Masaaki، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
3
From page
7019
To page
7021
Abstract
A kinetically stabilized 1,3,6-triphosphafulvene displayed regioselective reactivity toward nucleophiles at the external phosphorus atom (position 6) to afford the corresponding phosphinodiphospholide anions, which gave phosphinodiphospholes after quenching with electrophiles, as well as being readily reduced by sodium naphthalenide suggesting properties similar to fulvenes.
Keywords
phosphaalkenes , Reduction , Conjugated system , Nucleophilic reaction , regioselectivity
Journal title
Tetrahedron Letters
Serial Year
2004
Journal title
Tetrahedron Letters
Record number
1843261
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