Author/Authors :
Lin، نويسنده , , Ching-Wen and Lin، نويسنده , , Chi-Ching and Lam، نويسنده , , Louis F.-L. and Au-Yeung، نويسنده , , Terry T.-L. and Chan، نويسنده , , Albert S.C.، نويسنده ,
Abstract :
A novel chiral bisphosphinamidite ligand SpiroNP has been synthesized. The rhodium complex of this ligand has been found to be highly active and enantioselective in the asymmetric hydrogenation of (Z)-2-acetamidoacrylic acid derivatives and α,β-unsaturated carboxylic acid derivatives.