Title of article
trans-2-Aminocyclohexanols as pH-triggers for conformationally controlled crowns and podands
Author/Authors
Samoshin، نويسنده , , Vyacheslav V. and Chertkov، نويسنده , , Vyacheslav A. and Gremyachinskiy، نويسنده , , Dmitriy E. and Dobretsova، نويسنده , , Elena K. and Shestakova، نويسنده , , Alla K. and Vatlina، نويسنده , , Lidia P.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
4
From page
7823
To page
7826
Abstract
Protonation of trans-2-aminocyclohexanols leads to dramatic conformational changes: due to an intramolecular hydrogen bond a conformer with equatorial position of ammonio- and hydroxy-groups becomes predominant. The trans-2-aminocyclohexanol moiety has been used for pH-induced conformational switching of a crown ether and a podand.
Keywords
trans-2-Aminocyclohexanol , pH-switch , Conformations , Cyclohexano crown ether
Journal title
Tetrahedron Letters
Serial Year
2004
Journal title
Tetrahedron Letters
Record number
1843556
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