Title of article :
Twofold Brook rearrangement-mediated tandem reactions of δ-silyl-γ,δ-epoxy-α,β-unsaturated acylsilanes with a cyanide ion
Author/Authors :
Tanaka، نويسنده , , Koudai and Takeda، نويسنده , , Kei، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2004
Abstract :
Reaction of δ-silyl-γ,δ-epoxy-α,β-unsaturated acylsilanes with KCN in the presence of chloro or cyanoformates gives highly functionalized dienol silyl ether derivatives via a twofold Brook rearrangement-induced tandem sequence.
Keywords :
Tandem reaction , Brook rearrangement , Acylsilanes , Epoxysilanes
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
