Title of article
Synthesis and structural and electronic properties of the diacetylene- and ethylene-groups connected octaethylporphyrin(Ni) tetramer
Author/Authors
Hayashi، نويسنده , , Naoto and Naoe، نويسنده , , Azusa and Miyabayashi، نويسنده , , Keiko and Yamada، نويسنده , , Mami and Miyake، نويسنده , , Mikio and Higuchi، نويسنده , , Hiroyuki، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
5
From page
8215
To page
8219
Abstract
The tetramer of octaethylporphyrin nickel complex [OEP(Ni)], connected with diacetylene and ethylene linkages, was synthesized. Its structural and electronic properties were studied, proving that two constituents of the diacetylene-group connected OEP(Ni) dimer face to each other in s-cis conformation about the ethylene linkage but not so closely as to induce a transannular π-electronic interaction between them.
Keywords
Nickel complex , Diacetylene , ethylene , tetramer , Octaethylporphyrin
Journal title
Tetrahedron Letters
Serial Year
2004
Journal title
Tetrahedron Letters
Record number
1843720
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