Title of article :
A mechanistic study of the Hiyama–Nozaki allylation: evidence for radical intermediates
Author/Authors :
Mulzer، نويسنده , , Johann and Strecker، نويسنده , , Achim R. and Kattner، نويسنده , , Lars، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2004
Abstract :
In course of chromium(II) mediated additions of relatively complex allylic bromides to aldehydes (Hiyama–Nozaki allylation) radical intermediates have been observed. From these findings a new mechanism of the allylation is derived.
Keywords :
Organochromium compounds , Stereoselective allylation of aldehydes , Homoallylic alcohols , Allylic radicals , SET mechanism
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
