Title of article :
Rhodium-catalyzed carbonyl allylations by allylic alcohols with tin(II) chloride
Author/Authors :
Masuyama، نويسنده , , Yoshiro and Kaneko، نويسنده , , Yusuke and Kurusu، نويسنده , , Yasuhiko، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2004
Abstract :
Rhodium complexes such as [RhCl(cod)]2, [Rh(cod)2]BF4, and [Rh(cod)(CH3CN)2]BF4 function as catalysts for carbonyl allylations by allylic alcohols with 1 equimolar amount of tin(II) chloride to each allylic alcohol and aldehyde in THF at 50 °C to produce the corresponding homoallylic alcohols.
Keywords :
Carbonyl allylation , ?-Allylrhodium , Tin(II) chloride , nucleophilic addition
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
