Title of article :
Chiral phosphine oxide BINAPO as a catalyst for enantioselective allylation of aldehydes with allyltrichlorosilanes
Author/Authors :
Nakajima، نويسنده , , Makoto and Kotani، نويسنده , , Shunsuke and Ishizuka، نويسنده , , Tadao and Hashimoto، نويسنده , , Shunichi، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2005
Abstract :
The effectiveness of chiral phosphine oxide BINAPO as a catalyst for the enantioselective addition of allyltrichlorosilanes to aldehydes was demonstrated, wherein the combination of diisopropylethylamine and tetrabutylammonium iodide as additives is crucial for accelerating the catalytic cycle.
Keywords :
allylation , Catalyst , Enantioselectivity , Phosphine oxide
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
