• Title of article

    Tricoordinate diphenylboron cation prepared in solution

  • Author/Authors

    Uddin، نويسنده , , Md. Khabir and Nagano، نويسنده , , Yoshiya and Fujiyama، نويسنده , , Ryoji and Kiyooka، نويسنده , , Syun-ichi and Fujio، نويسنده , , Mizue and Tsuno، نويسنده , , Yuho، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2005
  • Pages
    4
  • From page
    627
  • To page
    630
  • Abstract
    Treatment of diphenylchloroborane with 1 equiv of pyridine or pyridine-N-oxide in CD2Cl2 formed the corresponding 1:1 adduct, which gave tricoordinate diphenylboron cation by electrophilic abstraction of chloride ion with the strong Lewis acid, SbCl5. The experimental 11B chemical shifts were in good agreement with the ab initio calculation results and the optimized structures were well explicable by 11B, 13C, and 121Sb NMR spectroscopy.
  • Keywords
    Diphenylboron cation , 11B NMR , Ab initio calculation
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2005
  • Journal title
    Tetrahedron Letters
  • Record number

    1844559

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1844559