Title of article
Ruthenium-catalyzed generation of hydrogen from iso-propanol
Author/Authors
Junge، نويسنده , , Henrik and Beller، نويسنده , , Matthias، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
4
From page
1031
To page
1034
Abstract
The dehydrogenation reaction of iso-propanol has been investigated in the absence of a hydrogen acceptor. Among different transition metals tested various ruthenium precursors in the presence of phosphine ligands proved to be active catalysts. Best results (turnover frequencies up to 155 h−1 after 2 h) were achieved with RuCl3·xH2O and 2-di-tert-butyl-phosphinyl-1-phenyl-1H-pyrrole 4 at low temperature (90 °C).
Journal title
Tetrahedron Letters
Serial Year
2005
Journal title
Tetrahedron Letters
Record number
1844723
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