• Title of article

    Rhodium-catalyzed synthesis of isothiocyanate from isonitrile and sulfur

  • Author/Authors

    Arisawa، نويسنده , , Mieko and Ashikawa، نويسنده , , Masanori and Suwa، نويسنده , , Atsushi and Yamaguchi، نويسنده , , Masahiko، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2005
  • Pages
    3
  • From page
    1727
  • To page
    1729
  • Abstract
    Rhodium complexes RhH(PPh3)4 and Rh(acac)(CH2CH2)2 catalyze sulfuration of isonitrile with sulfur giving isothiocyanates in high yields. The metal-catalyzed reaction is rapid in refluxing acetone, and completes within 3 h in most cases. The reaction exhibits induction period, which disappeared by preheating sulfur in refluxing acetone for 1.5 h. Use of several organic polysulfides in this transformation was examined in order to compare the reactivity.
  • Keywords
    Isonitrile , Induction Period , Rhodium complex , Isothiocyanate , Sulfur
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2005
  • Journal title
    Tetrahedron Letters
  • Record number

    1845024

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1845024