Title of article :
Solvent effects in a carbenoid N–H insertion route to triarylamines via 2-diazo-1,3-cyclohexanedione
Author/Authors :
Livant، نويسنده , , Peter and Jie، نويسنده , , Yuanping and Wang، نويسنده , , Xing، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2005
Abstract :
The Rh-carbenoid derived from 2-diazo-1,3-cyclohexanedione inserts into the N–H bond of arylalkylamines and diarylamines. A solvent for this reactive carbenoid is suggested. The insertion products undergo a Pd-mediated aromatization to afford alkyldiarylamines and triarylamines.
Keywords :
Triarylamines , rhodium carbenoid , aromatization , N–H insertion , Rh2(OAc)4 , Pd(CH3CN)2Cl2 , Solvent effect
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
