Author/Authors :
Ortiz، نويسنده , , Aurelio and Hernلndez، نويسنده , , Hector and Mendoza، نويسنده , , Guadalupe and Quintero، نويسنده , , Leticia and Bernès، نويسنده , , Sylvain، نويسنده ,
Abstract :
Chiral 3-methylthio alcohols have been synthesized through a known intramolecular sulfur transfer reaction that has been carried out in di- and trisubstituted α,β-unsaturated N-enoyl oxazolidinethiones as substrates, giving rise to syn/anti-diastereomers. The anti-diastereomer is favored and obtained via a highly diastereoselective protonation step.
