Title of article
Asymmetric synthesis of 3-methylthio alcohols by intramolecular Michael addition reactions
Author/Authors
Ortiz، نويسنده , , Aurelio and Hernلndez، نويسنده , , Hector and Mendoza، نويسنده , , Guadalupe and Quintero، نويسنده , , Leticia and Bernès، نويسنده , , Sylvain، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
4
From page
2243
To page
2246
Abstract
Chiral 3-methylthio alcohols have been synthesized through a known intramolecular sulfur transfer reaction that has been carried out in di- and trisubstituted α,β-unsaturated N-enoyl oxazolidinethiones as substrates, giving rise to syn/anti-diastereomers. The anti-diastereomer is favored and obtained via a highly diastereoselective protonation step.
Journal title
Tetrahedron Letters
Serial Year
2005
Journal title
Tetrahedron Letters
Record number
1845216
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