Title of article
A silver-catalyzed Büchner reaction
Author/Authors
Lovely، نويسنده , , Carl J. and Browning، نويسنده , , R. Greg and Badarinarayana، نويسنده , , Vivek and Dias، نويسنده , , H.V. Rasika، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
3
From page
2453
To page
2455
Abstract
A silver scorpionate complex, derived from the highly fluorinated [HB(3,5-(CF3)2Pz)3]−, catalyzes the addition of ethyl diazoacetate to benzene rings, providing norcaradienes, which undergo electrocyclization to provide the corresponding cycloheptatriene. These reactions are surprisingly selective for addition to the aromatic moiety rather than C–H insertion.
Keywords
Scorpionates , Carbene , Catalysis , ring-expansion
Journal title
Tetrahedron Letters
Serial Year
2005
Journal title
Tetrahedron Letters
Record number
1845293
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