• Title of article

    Montmorillonite K-10 as a mild acid for the Nicholas reaction

  • Author/Authors

    Crisَstomo، نويسنده , , Fernando R. Pinacho and Carrillo، نويسنده , , Romen and Martيn، نويسنده , , Tomلs and Martيn، نويسنده , , Vيctor S.، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2005
  • Pages
    4
  • From page
    2829
  • To page
    2832
  • Abstract
    The use of Montmorillonite K-10 as a convenient acid component in the Nicholas reaction is described. Its use permits functional selectivity, inter- and intramolecular reactions and convenience in the experimental conditions. A four-step one-pot [Co2(CO)6–acetylene complex formation, THP-removal, cyclization and complex cleavage] process permits the direct synthesis of 2-ethynyl-tetrahydrofuran from 6-(tetrahydro-2H-pyran-2-yloxy)hex-1-yn-3-ol.
  • Keywords
    Cyclic ether , Cobalt , Nicholas reaction
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2005
  • Journal title
    Tetrahedron Letters
  • Record number

    1845425

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1845425