Title of article
Highly efficient asymmetric transfer hydrogenation of ketones catalyzed by chiral ‘roofed’ cis-diamine–Ru(II) complex
Author/Authors
Matsunaga، نويسنده , , Hirofumi and Ishizuka، نويسنده , , Tadao and Kunieda، نويسنده , , Takehisa، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
4
From page
3645
To page
3648
Abstract
A new type of chiral Ru(II) complex, prepared from a conformationally rigid, sterically bulky ‘roofed’ cis-diamine and [RuCl2(benzene)]2, functions as an efficient catalyst for the asymmetric transfer hydrogenation of a wide variety of aryl ketones, including sterically bulky ketones, when the reaction is conducted in the presence of 5HCO2H·2NEt3.
Keywords
Asymmetric transfer hydrogenation , 5HCO2H·2NEt3 , Aryl ketones , cis-diamine–Ru(II) complex
Journal title
Tetrahedron Letters
Serial Year
2005
Journal title
Tetrahedron Letters
Record number
1845716
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