Title of article
Novel generation of selenoaldehydes through stannic chloride-induced unsymmetrical C–Se bond cleavage of bis(N,N-dimethylcarbamoylseleno)methanes
Author/Authors
Shimada، نويسنده , , Kazuaki and Gong، نويسنده , , Yaling and Nakamura، نويسنده , , Hidenori and Matsumoto، نويسنده , , Rei and Aoyagi، نويسنده , , Shigenobu and Takikawa، نويسنده , , Yuji، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
4
From page
3775
To page
3778
Abstract
Treatment of a benzene or a CH2Cl2 solution of bis(N,N-dimethylcarbamoylseleno)methanes with SnCl4 afforded β-1,3,5-triselenanes, and the key intermediates, acylselonium ions and selenoaldehydes, were successfully trapped by using allyltrimethylsilane or 2,3-dimethyl-1,3-butadiene to obtain the allylation products or the cycloadducts, respectively.
Keywords
Acylselonium ion , 5-Triselenane , Bis(N , N-dimethylcarbamoylseleno)methane , Diselenoacetal , selenoaldehyde , ?-1 , 3
Journal title
Tetrahedron Letters
Serial Year
2005
Journal title
Tetrahedron Letters
Record number
1845773
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