Title of article
Spectroscopic and DFT evidence for a nonclassical radical cation derived from 7-benzhydrylidenenorbornene
Author/Authors
Ikeda، نويسنده , , Hiroshi and Namai، نويسنده , , Hayato and Hirano، نويسنده , , Takashi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
5
From page
3917
To page
3921
Abstract
Nanosecond time-resolved UV/vis absorption spectroscopy on laser flash photolysis was conducted for photoinduced electron-transfer reactions of 7-benzhydrylidenenorbornene (1) and 7-benzhydrylidenenorbornane (5). The differences in the observed absorption bands and the structures of 1+ and 5+ were evaluated successfully using calculations based on (time dependent) density functional theory, confirming the nonclassical nature of 1+.
Keywords
electronic coupling , ?-Facial selectivity , photochemistry , Nonclassical radical cation , absorption spectra
Journal title
Tetrahedron Letters
Serial Year
2005
Journal title
Tetrahedron Letters
Record number
1845826
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