Title of article
Enantioselective conjugate addition of diethylzinc to acyclic enones using a copper phosphino-phenol complex as catalyst
Author/Authors
Ito، نويسنده , , Katsuji and Eno، نويسنده , , Shuuichiro and Saito، نويسنده , , Bunnai and Katsuki، نويسنده , , Tsutomu، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
5
From page
3981
To page
3985
Abstract
Newly designed phosphino-phenol 1c was found to be an efficient chiral auxiliary for copper-mediated asymmetric conjugate addition of diethylzinc to acyclic enones. High enantioselectivity up to >99% ee was achieved in the reaction of acyclic α,β-enones.
Keywords
Copper , Phosphino-phenol , conjugate addition , Asymmetric catalysis
Journal title
Tetrahedron Letters
Serial Year
2005
Journal title
Tetrahedron Letters
Record number
1845854
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