Author/Authors :
Sugimoto، نويسنده , , Takahiro and Sada، نويسنده , , Kazuki and Tateishi، نويسنده , , Yuichi and Suzuki، نويسنده , , Takayuki and Sei، نويسنده , , Yoshihisa and Yamaguchi، نويسنده , , Kentaro and Shinkai، نويسنده , , Seiji، نويسنده ,
Abstract :
A new strategy to control the orientation and aggregation numbers of porphyrins by alignment along well-defined templates has been demonstrated. Porphyrin-bridged bisPYBOX ligands were arranged along the oligomeric secondary dialkylammonium cations as templates to form well-defined supramolecular complexes. The templates controlled the aggregations of the porphyrins.
Keywords :
Aggregate , template , Ladder-type assembly , Porphyrin , Hydrogen bonding