Title of article
BINOL-derived N-phosphino sulfoximines as ligands for asymmetric catalysis
Author/Authors
Reetz، نويسنده , , Manfred T. and Bondarev، نويسنده , , Oleg G. and Gais، نويسنده , , Hans-Joachim and Bolm، نويسنده , , Carsten، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
4
From page
5643
To page
5646
Abstract
BINOL-derived N-phosphino sulfoximines have been prepared for the first time and tested as ligands in asymmetric transition metal catalysis. Up to 99% ee was achieved in the Rh-catalyzed asymmetric hydrogenation of functionalized olefins and up to 66% ee in the Pd-catalyzed allylic alkylation.
Keywords
Hydrogenation , allylation , Asymmetric reactions , N-Phosphino sulfoximines , Rhodium
Journal title
Tetrahedron Letters
Serial Year
2005
Journal title
Tetrahedron Letters
Record number
1846439
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