Title of article :
The highly enantioselective Diels–Alder reaction of 1,2-dihydropyridine using chiral cationic palladium–phosphinooxazolidine catalyst for the synthesis of chiral isoquinuclidines
Author/Authors :
Nakano، نويسنده , , Hiroto and Tsugawa، نويسنده , , Natsumi and Fujita، نويسنده , , Reiko، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2005
Abstract :
The enantioselective Diels–Alder reactions of 1-phenoxycarbonyl-1,2-dihydropyridine with 1-alkylated acryloyl-pyrazolidin-3-ones using chiral cationic palladium–phosphinooxazolidine (Pd–POZ) catalyst afforded chiral isoquinuclidines with excellent enantioselectivity (up to 97% ee).
Keywords :
1 , 2-dihydropyridine , Chiral isoquinuclidines , enantioselective Diels–Alder reaction , Chiral cationic palladium–phosphinooxazolidine catalyst
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
