Title of article :
A one-pot process for the enantioselective preparation of saturated secondary alcohols from propargyl ketones under hydrogen transfer conditions
Author/Authors :
Bogliotti، نويسنده , , Nicolas and Dalko، نويسنده , , Peter I. and Cossy، نويسنده , , Janine، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2005
Abstract :
Propargyl ketones can be directly transformed to enantio-enriched saturated secondary alcohols in a one-pot reaction using chiral RuCl[N-(tosyl)-1,2-diphenylethylenediamine)(p-cymene) and Pd/BaSO4 as catalysts, under transfer hydrogenation conditions.
Keywords :
Alkynes , alcohols , Catalysis , asymmetric synthesis , Hydrogenation , Reduction
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
