Title of article :
Synthesis of oligomers including eight P-chiral centers and the construction of the 12-phosphacrown-4 skeleton
Author/Authors :
Morisaki، نويسنده , , Yasuhiro and Ouchi، نويسنده , , Yuko and Fukui، نويسنده , , Tatsuki and Naka، نويسنده , , Kensuke and Chujo، نويسنده , , Yoshiki، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2005
Abstract :
The stepwise oxidative coupling reaction from (S,S)-1 gave optically active oligomers, (S,R,R,S)-2 and (S,R,S,R,R,S,R,S)-3, having four and eight chiral phosphorus atoms, respectively. The behaviors of these oligomers in the solid state and in solution were investigated in detail. The first construction of a 12-phosphacrown-4 skeleton was also reported.
Keywords :
Chiral phosphorus atoms , Oxidative coupling reaction , Optically active oligomer , 12-Phosphacrown-4
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
