Title of article :
Pd-catalyzed desulfonylative homocoupling of arenesulfonyl chlorides in the presence of hexamethyldisilane forming biaryls
Author/Authors :
Kashiwabara، نويسنده , , Taigo and Tanaka، نويسنده , , Masato، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2005
Abstract :
Arenesulfonyl chlorides undergo desulfonylative homo-coupling upon heating with hexamethyldisilane in the presence of Pd2(dibenzylideneacetone)3·CHCl3 as a precatalyst to afford biaryls. Diaryl sulfides are occasionally formed as byproducts.
Keywords :
sulfonyl chloride , desulfonylation , Homogeneous catalysis , PALLADIUM
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
