• Title of article

    The first example of the configurational assignment at the CN bond of allenylthioimidates

  • Author/Authors

    Krivdin، نويسنده , , Leonid B. and Nedolya، نويسنده , , Nina A.، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2005
  • Pages
    5
  • From page
    7367
  • To page
    7371
  • Abstract
    Configurational assignment of methyl 2-methoxy-N-methyl-2,3-butadienimidothioate, a representative member of a new prospective allenylthioimidates series has been performed by means of low-temperature natural-abundance J(C,C) measurements in combination with the high-level ab initio SOPPA calculations. Electronic structure and predominant conformations of the isomers of the title allenylthioimidate are discussed based on the DFT-B3LYP calculations.
  • Keywords
    SOPPA , DFT-B3LYP , Allenylthioimidates , E–Z Isomers , conformational analysis , NMR , Carbon–carbon spin–spin coupling constants
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2005
  • Journal title
    Tetrahedron Letters
  • Record number

    1847013