Title of article
Selective cis-addition of C–H bonds of pyrroles and thiophenes to alkynes catalyzed by a dinuclear palladium complex
Author/Authors
Tsukada، نويسنده , , Naofumi and Murata، نويسنده , , Kazuko and Inoue، نويسنده , , Yoshio، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
3
From page
7515
To page
7517
Abstract
Pyrroles and thiophenes reacted with alkynes in the presence of dinuclear palladium complexes with high stereoselectivity (cis-addition) in almost all cases. While regioselectivity in the reaction with pyrroles depended on substituents on the nitrogen atom and alkynes, all reactions of thiophenes afforded 2-alkenylthiophenes.
Keywords
Heteroarene , PALLADIUM , Dinuclear complexes , alkyne , Catalysis , C–H activation
Journal title
Tetrahedron Letters
Serial Year
2005
Journal title
Tetrahedron Letters
Record number
1847083
Link To Document