Title of article
TiCl3/PhN2+-mediated radical addition of ethers to aldimines generated in situ under aqueous conditions
Author/Authors
Clerici، نويسنده , , Angelo and Cannella، نويسنده , , Rosalba and Panzeri، نويسنده , , Walter and Pastori، نويسنده , , Nadia and Regolini، نويسنده , , Eva and Porta، نويسنده , , Ombretta، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
4
From page
8351
To page
8354
Abstract
Ti(III)-mediated one-electron reduction of phenyldiazonium cation, followed by phenyl radical α-H atom abstraction from ethers, leads to one-pot radical addition of ethers to the C-atom of imines generated in situ from the corresponding aldehydes and imines under aqueous conditions. The reaction is not limited to aromatic aldehydes and may be applied to imines generated in situ from formaldehyde and enolizable aldehydes.
Keywords
radical addition , Aldimines , Three-component reaction , Titanium trichloride , one-electron reduction
Journal title
Tetrahedron Letters
Serial Year
2005
Journal title
Tetrahedron Letters
Record number
1847731
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