Author/Authors :
Clerici، نويسنده , , Angelo and Cannella، نويسنده , , Rosalba and Panzeri، نويسنده , , Walter and Pastori، نويسنده , , Nadia and Regolini، نويسنده , , Eva and Porta، نويسنده , , Ombretta، نويسنده ,
Abstract :
Ti(III)-mediated one-electron reduction of phenyldiazonium cation, followed by phenyl radical α-H atom abstraction from ethers, leads to one-pot radical addition of ethers to the C-atom of imines generated in situ from the corresponding aldehydes and imines under aqueous conditions. The reaction is not limited to aromatic aldehydes and may be applied to imines generated in situ from formaldehyde and enolizable aldehydes.
Keywords :
radical addition , Aldimines , Three-component reaction , Titanium trichloride , one-electron reduction
