An unexpected inversion of enantioselectivity in the proline catalyzed intramolecular Baylis–Hillman reaction
Author/Authors :
Chen، نويسنده , , Shang-Hung and Hong، نويسنده , , Bor-Cherng and Su، نويسنده , , Cheng-Feng and Sarshar، نويسنده , , Sepehr، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2005
Pages :
5
From page :
8899
To page :
8903
Abstract :
A highly enantioselective proline catalyzed intramolecular Baylis–Hillman reaction of hept-2-enedial is reported. Addition of imidazole to the mixture results in an unusual inversion of enantioselectivity.
