Title of article
One-pot selective oxidation/olefination of primary alcohols using TEMPO–BAIB system and stabilized phosphorus ylides
Author/Authors
Jean-Michel Vatèle، نويسنده , , Jean-Michel، نويسنده ,
Issue Information
دوماهنامه با شماره پیاپی سال 2006
Pages
4
From page
715
To page
718
Abstract
A one-pot process for the synthesis of α,β-unsaturated esters from a variety of alcohols, obtained in good yields and diastereoselectivities, is described. The use of BAIB/TEMPO system at the oxidizing step authorizes the chemoselective homologation of primary alcohols in the presence of secondary ones.
Keywords
Unsaturated esters , Bis(acetoxy)iodobenzene (BAIB) , Olefination , 6-Tetramethyl-1-piperidinyloxy (TEMPO) , Oxidation , 2 , 2 , 6
Journal title
Tetrahedron Letters
Serial Year
2006
Journal title
Tetrahedron Letters
Record number
1848582
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