Title of article
Reductive cyclisation of Morita–Baylis–Hillman adducts. A simple approach towards substituted hydrindanones and decalones
Author/Authors
Bernard and Wasnaire، نويسنده , , Pierre and Wiaux، نويسنده , , Marianne and Touillaux، نويسنده , , Roland and Markَ، نويسنده , , Istvلn E.، نويسنده ,
Issue Information
دوماهنامه با شماره پیاپی سال 2006
Pages
5
From page
985
To page
989
Abstract
A connective synthesis of substituted hydrindanones and decalones can be accomplished based upon a novel approach involving two key-steps: a Morita–Baylis–Hillman condensation and an intramolecular reductive cyclisation using lithium in ammonia. Decalones, akin to the middle core of the clerodane family of natural products and bearing a quaternary carbon centre, can be readily assembled via this protocol.
Keywords
Morita–Baylis–Hillman reaction , Hydrindanes , Decalins , lithium , Reductive cyclisation
Journal title
Tetrahedron Letters
Serial Year
2006
Journal title
Tetrahedron Letters
Record number
1848764
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