Title of article
Visible light induced ‘on water’ benzylic bromination with N-bromosuccinimide
Author/Authors
Podgor?ek، نويسنده , , Ajda and Stavber، نويسنده , , Stojan and Zupan، نويسنده , , Marko and Iskra، نويسنده , , Jernej، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2006
Pages
3
From page
1097
To page
1099
Abstract
Benzylic bromination of various 4-substituted toluenes (Me, tert-Bu, COOEt and COMe) was effectively conducted with NBS in pure water and with a 40 W incandescent light-bulb as an initiator of the radical chain process, while electron donating groups (OMe and NHAc) directed the reaction to electrophilic aromatic substitution.
Keywords
water , Halogenation , Benzyl bromination , radical reactions , aqueous media , N-Bromosuccinimide
Journal title
Tetrahedron Letters
Serial Year
2006
Journal title
Tetrahedron Letters
Record number
1848804
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