Title of article
A synthetic study of briarane-type marine diterpenoid, pachyclavulide B
Author/Authors
Iwasaki، نويسنده , , Junya and Ito، نويسنده , , Hisanaka and Nakamura، نويسنده , , Mitsutake and Iguchi، نويسنده , , Kazuo، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2006
Pages
4
From page
1483
To page
1486
Abstract
Enantioselective preparation of the six-membered ring of pachyclavulide B, a briarane-type diterpenoid, was achieved. The key step is desymmetrization of an achiral symmetric substrate by enantiogroup- and diastereoselective epoxidation. The asymmetric epoxidation proceeded with up to 99% de and 94% ee.
Journal title
Tetrahedron Letters
Serial Year
2006
Journal title
Tetrahedron Letters
Record number
1849039
Link To Document