Author/Authors :
Hirashita، نويسنده , , Tsunehisa and Toumatsu، نويسنده , , Shinya and Imagawa، نويسنده , , Yuri and Araki، نويسنده , , Shuki and Setsune، نويسنده , , Jun-ichiro، نويسنده ,
Abstract :
Allylindium reagents allylated azirines to give allylaziridines in good yields. The delivery of the allyl group was well regulated by the substituents at the C3-carbon of azirines. The cis-allylation with respect to the substituent was realized with azirines bearing a hydroxylmethyl or an acetoxymethyl group due to the chelation with allylindium reagents, whereas the trans-allylation was achieved with azirines substituted by a methyl, phenyl, or ester group owing to the steric repulsion.
