Title of article :
Is diazomethane addition to chiral α-keto esters subject to substrate diastereocontrol?
Author/Authors :
Petronijevic، نويسنده , , Filip and Hart، نويسنده , , Amy C. and Paquette، نويسنده , , Leo A.، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2006
Abstract :
The uncatalyzed reaction of diazomethane with chiral benzoylformate esters results in the formation of α-oxiranyl esters without significant facial discrimination in almost every case.
Keywords :
Diastereoselective methylene transfer , Benzoylformate esters , glycidic esters , Asymmetric induction
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
