Title of article
Chiral bidentate phosphabenzene-based ligands: synthesis, coordination chemistry, and application in Rh-catalyzed asymmetric hydrogenations
Author/Authors
Müller، نويسنده , , Christian and Lَpez، نويسنده , , Leire Guarrotxena and Kooijman، نويسنده , , Huub and Spek، نويسنده , , Anthony L. and Vogt، نويسنده , , Dieter، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2006
Pages
4
From page
2017
To page
2020
Abstract
Novel hydroxy-functionalized phosphabenzenes were synthesized, which provide the possibility to prepare chiral phosphabenzene–phosphites. These systems act as bidentate ligands toward rhodium centers and the corresponding metal complexes were applied in the rhodium-catalyzed asymmetric hydrogenation of prochiral substrates.
Keywords
Phosphabenzenes , Homogeneous catalysis , Phosphites , asymmetric hydrogenation , Rhodium
Journal title
Tetrahedron Letters
Serial Year
2006
Journal title
Tetrahedron Letters
Record number
1849288
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