Title of article
A facile synthesis of chiral polyazamacrocycles and the UV spectroscopic and CD spectra studies on metal complexes
Author/Authors
Ai، نويسنده , , Lin and Xiao، نويسنده , , Jichuan and Shen، نويسنده , , Xiumin and Zhang، نويسنده , , Cong، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2006
Pages
5
From page
2371
To page
2375
Abstract
A series of chiral polyazamacrocycles with 12, 18, 24, 27, 36-membered rings were designed and synthesized using (S)-α-phenylethylamine as initial chiral source. Herein 11 new chiral polyazamacrocycles were successfully prepared. The UV spectroscopic titration experiments of polyazamacrocycle 3b with metal ions were carried out and the binding constants and free energy changes were calculated according to the modified Benesi–Hildebrand equation. Circular dichroism spectra were recorded for 3b with metal ions.
Keywords
Polyazamacrocycles , Synthesis , CD spectra , UV spectroscopic
Journal title
Tetrahedron Letters
Serial Year
2006
Journal title
Tetrahedron Letters
Record number
1849432
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