Author/Authors :
Titz، نويسنده , , Alexander and Radic، نويسنده , , Zorana and Schwardt، نويسنده , , Oliver G. Ernst، نويسنده , , Beat، نويسنده ,
Abstract :
A safe and convenient method for the copper(II)-catalyzed diazo transfer from triflyl azide to primary amines is reported. By replacing CH2Cl2 by toluene the formation of hazardous side products, for example, azido-chloromethane and diazidomethane can be avoided.