Title of article
Evidence of the central tetrathiafulvalene bond opening by copper(II) salts. In situ generation of 2,3-bis(2′-cyanoethylchalcogeno)-7,8-benzo-1,4,6,9-tetrathia-10-ceto spiro[4,5]decane
Author/Authors
Boudiba، نويسنده , , Louiza and Ouahab، نويسنده , , Lahcène and Gouasmia، نويسنده , , Abdelkrim، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2006
Pages
3
From page
3123
To page
3125
Abstract
The two-electrons oxidation of 4,5-benzo-6,7-bis(2′-cyanoethylthio) TTF (CETBz-TTF) and 4,5-benzo-6,7-bis(2′-cyanoethylseleno) TTF (CESBz-TTF) with Cu2+X2 (X = Cl−, BF 4 - ) leads to the formation of 2,3-bis(2′-cyanoethylchalcogeno)-7,8-benzo-1,4,6,9-tetrathia-10-ceto spiro[4,5]decane after opening of the –C–S– bond of the central TTF core.
Keywords
Benzo-tetrathiafulvalene , Copper(II) , Rearrangement , Electron oxidation , Opening central TTF bond
Journal title
Tetrahedron Letters
Serial Year
2006
Journal title
Tetrahedron Letters
Record number
1849877
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