Author/Authors :
Tomé، نويسنده , , Joمo P.C. and Cho، نويسنده , , Dong-Gyu and Sessler، نويسنده , , Jonathan L. and Neves، نويسنده , , Maria G.P.M.S. and Tomé، نويسنده , , Augusto C. and Silva، نويسنده , , Artur M.S. and Cavaleiro، نويسنده , , José A.S.، نويسنده ,
Abstract :
Sapphyrins participate in Diels–Alder reactions with pentacene affording novel barrelene-fused sapphyrins. The new compounds were synthesized using traditional heating and microwave irradiation conditions. The experiments carried out under microwave irradiation proved cleaner, affording only the monoadduct and in higher yields.
Keywords :
pentacene , Diels–Alder reactions , sapphyrins , Barrelene , microwave irradiation