Title of article
An efficient and rapid chalcogenide-Morita–Baylis–Hillman process promoted by TBDMSOTf and a thiolane
Author/Authors
Rao، نويسنده , , Jamjanam Srivardhana and Brière، نويسنده , , Jean-François and Metzner، نويسنده , , Patrick and Basavaiah، نويسنده , , Deevi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2006
Pages
4
From page
3553
To page
3556
Abstract
The ability of the combination of sulfide/TBDMSOTf to promote a chalcogenide-Morita–Baylis–Hillman reaction is reported. The original Michael–Mukaiyama-retroaldol sequence took place and furnished the MBH adducts from the corresponding enones and acetals. This one step process could be performed smoothly at low temperatures (−20 to −50 °C) and is rapidly completed within a few hours.
Keywords
Chalcogenide-Morita–Baylis–Hillman , TBDMSOTf , Sulfide , enone , acetal
Journal title
Tetrahedron Letters
Serial Year
2006
Journal title
Tetrahedron Letters
Record number
1850362
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