Author/Authors :
Lei، نويسنده , , Lei and Wu، نويسنده , , Li-Zhu and Wu، نويسنده , , Xiao-Ling and Liao، نويسنده , , Gui-Hong and Luo، نويسنده , , Lin and Zhang، نويسنده , , Li-Ping and Tung، نويسنده , , Chen-Ho and Ding، نويسنده , , Kui-Ling، نويسنده ,
Abstract :
A novel type of C2-symmetric-chiral ligand, based on a cubane-like photodimer 1 of methyl 2-naphthoate, is reported in this work. Crystal analysis reveals that the methyl carboxylate functionality is in an anti-head-to-head conformation and 1 is highly rigid. The optically pure enantiomers of 1 can be obtained simply by HPLC resolution.
Keywords :
Cubane-like photodimer , Stereochemistry , C2-Symmetric ligand , Methyl 2-naphthoate
