• Title of article

    A novel reduction reaction for the conversion of aldehydes, ketones and primary, secondary and tertiary alcohols into their corresponding alkanes

  • Author/Authors

    Nimmagadda، نويسنده , , Rama D. and McRae، نويسنده , , Christopher، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2006
  • Pages
    4
  • From page
    5755
  • To page
    5758
  • Abstract
    A novel one-pot reaction has been developed for the reduction of aldehydes, ketones and primary, secondary and tertiary alcohols into their corresponding alkyl function. This is also the first reported method which can efficiently reduce primary, secondary, or tertiary alcohols, without affecting carbon–carbon double bonds, into their corresponding alkyl function in high yields. The reduction utilises either diethylsilane or n-butylsilane as the reducing agent in the presence of the Lewis acid catalyst tris(pentafluorophenyl)borane.
  • Keywords
    Reduction , Aldehydes , ketones , alcohols , n-BS: n-butylsilane , B(C6F5)3: tris(pentafluorophenyl)borane , DES: diethylsilane
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2006
  • Journal title
    Tetrahedron Letters
  • Record number

    1851890