Title of article :
Total synthesis of 6-deoxyclitoriacetal isolated from Stemona collinsae Craib.
Author/Authors :
Prapas Khorphueng، نويسنده , , Prapas and Tummatorn، نويسنده , , Jumreang and Petsom، نويسنده , , Amorn and Taylor، نويسنده , , Richard J.K. and Roengsumran، نويسنده , , Sophon، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2006
Abstract :
A total synthesis of the rotenoid, 6-deoxyclitoriacetal, a cytotoxic natural product, was successfully achieved by using platinum-catalysed hydroarylation, Sharpless asymmetric dihydroxylation, regioselective IBX diol oxidation and stereoselective intramolecular keto-aldehyde pinacol coupling as the key steps.
Keywords :
Rotenoid , Samarium diiodide , Pinacol coupling
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
