Author/Authors :
Filippi، نويسنده , , Jean-Jacques and Fernandez، نويسنده , , Xavier and Duٌach، نويسنده , , Elisabet، نويسنده ,
Abstract :
Boron trifluoride and indium(III) trifluoromethanesulfonate were found to efficiently catalyse the isomerisation of thionolactones to thiolactones in good yields. When applied to an optically active γ-thionolactone, the isomerisation reaction proceeded with a complete inversion of configuration by using BF3·Et2O.
