Title of article
Magnesium(II)-coordinated Claisen rearrangement: a direct approach towards ulosonic acid derivatives
Author/Authors
Grison، نويسنده , , Claude and Olszewski، نويسنده , , Tomasz K. and Crauste، نويسنده , , Céline and Fruchier، نويسنده , , Alain and Didierjean، نويسنده , , Claude and Coutrot، نويسنده , , Philippe، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2006
Pages
4
From page
6583
To page
6586
Abstract
Unprecedented magnesium dihalide-catalysed Claisen rearrangement of 2-alkoxycarbonyl allyl vinyl ethers derived from α-chloroglycidic esters is reported in the glucidic series. A first application of this reaction concerns the stereoselective construction of a disaccharide analogue including a galactosyl and an ulosonic isopropyl ester moieties.
Keywords
Claisen rearrangement , Magnesium dihalide , Ulosonic esters , Disaccharide analogues , ?-chloroglycidic esters
Journal title
Tetrahedron Letters
Serial Year
2006
Journal title
Tetrahedron Letters
Record number
1852361
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