Title of article
The first example of samarium diiodide-promoted intramolecular ketone–ester coupling of ketones tethering acyloxyalkyl side chains producing 2-hydroxy cyclic hemiacetals
Author/Authors
Hasegawa، نويسنده , , Eietsu and Okamoto، نويسنده , , Kentaro and Tanikawa، نويسنده , , Naoko Hara-Nakamura، نويسنده , , Momoe and Iwaya، نويسنده , , Kazuki and Hoshi، نويسنده , , Takashi and Suzuki، نويسنده , , Toshio، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2006
Pages
4
From page
7715
To page
7718
Abstract
The reaction of samarium diiodide with some cyclic and acyclic ketones tethering acyloxyalkyl side chains produced 2-hydroxy cyclic hemiacetals in moderate to good yields, in which an intramolecular addition of samarium ketyl radicals to distant ester carbonyls would be involved.
Keywords
Samarium diiodide , Intramolecular ketone ester coupling , Cyclic hemiacetals
Journal title
Tetrahedron Letters
Serial Year
2006
Journal title
Tetrahedron Letters
Record number
1852964
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