Title of article
A synthesis of 2-fluoroglucal derivatives
Author/Authors
Boyd، نويسنده , , Ewan and Jones، نويسنده , , Ray V.H. and Quayle، نويسنده , , Peter and Waring (née Potts)، نويسنده , , Anita J.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2006
Pages
4
From page
7983
To page
7986
Abstract
3,4,6-Tri-O-methyl-d-glucal, readily prepared from 3,4,6-tri-O-acetyl-d-glucal, undergoes lithiation at −78 °C in THF with t-BuLi to afford a vinyl carbanion, which can be trapped with electrophiles in moderate overall yields. The palladium coupling and Dötz-type reactions of these intermediates are also described.
Keywords
Fluorosugar , lithiation , fluorine , glycal , metallation , glucal
Journal title
Tetrahedron Letters
Serial Year
2006
Journal title
Tetrahedron Letters
Record number
1853111
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