Author/Authors :
Wang، نويسنده , , Jiarui and Fu، نويسنده , , Yao and Zhang، نويسنده , , Beibei and Cui، نويسنده , , Xin and Liu، نويسنده , , Ting-Lei and Guo، نويسنده , , Qing-Xiang، نويسنده ,
Abstract :
Pd-Catalyzed aerobic oxidation of different amines was systematically examined for the first time. A PdCl2/PPh3 system was successfully developed to catalyze the aerobic oxidation of several types of amines including Ar–CH2NHPh, Ar–CH2NHOMe, and Ar–CH2NHMs with high yields. Theoretical studies showed a remarkable difference in the energy barriers of β-hydride elimination between an alcohol and various amines.
